A simple and effective method for fluoroalkylation——the addition of fluoroalkyl iodide to olefins in the presence of hydrogen peroxide

A simple and effective method for fluoroalkylation——the addition of fluoroalkyl iodide to olefins in the presence of hydrogen peroxide

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摘要 Addition of fluoroalkyl iodides to olefins in the presence of hydrogen peroxide(H_2O_(?)) in acetone,acetonitrile or ethanol gave the corresponding 1:1 adducts in good yields.Reaction of fluoroalkyl iodide with diallyl ether(DAE)yielded tetrahydrofuran derivatives,p-Hydroquinone (p-HQ)can partly suppress the reaction.A radical initiation mechanism is proposed. Addition of fluoroalkyl iodides to olefins in the presence of hydrogen peroxide(H_2O_(?)) in acetone,acetonitrile or ethanol gave the corresponding 1:1 adducts in good yields.Reaction of fluoroalkyl iodide with diallyl ether(DAE)yielded tetrahydrofuran derivatives,p-Hydroquinone (p-HQ)can partly suppress the reaction.A radical initiation mechanism is proposed.

作者 CHEN,Qing-Yun CHEN,Ming-Fang Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 1991年第2期184-188,共0页 中国化学（英文版）

基金 This project was supported by the National Natural Science Foundation of China.

关键词 A simple and effective method for fluoroalkylation the addition of fluoroalkyl iodide to olefins in the presence of hydrogen peroxide

分类号 O6 [理学—化学]

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Chinese Journal of Chemistry

1991年第2期

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A simple and effective method for fluoroalkylation——the addition of fluoroalkyl iodide to olefins in the presence of hydrogen peroxide

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