摘要
This paper presents a character table of S_4 wr S_2 wreath product group.Using this character table,~1H or ^(13)C NMR spectra analysis of molecula with S_4[S_2]symmetry,especially simplification of the secular determinant equation will be easy to carry out. Molecules with S_4[S_2]symmetry,are exemplified by octaphenylcyclo- tetrasiloxane and 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine chromium (Ⅲ)chloride.
This paper presents a character table of S_4 wr S_2 wreath product group.Using this character table,~1H or ^(13)C NMR spectra analysis of molecula with S_4[S_2]symmetry,especially simplification of the secular determinant equation will be easy to carry out. Molecules with S_4[S_2]symmetry,are exemplified by octaphenylcyclo- tetrasiloxane and 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine chromium (Ⅲ)chloride.