PHOTOSENSITIVITY OF CERIC ION INITIATED METHYL ACRYLATE POLYMERIZATION

PHOTOSENSITIVITY OF CERIC ION INITIATED METHYL ACRYLATE POLYMERIZATION

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摘要 The polymerization of methyl acrylate was sensitive to UV light. Under UV light,the rate of polymerization is 8 times as high as the rate in dark.The overall activation energy was decreased by the UV light (313nm).A tentative explanation is given and the mechanism is discussed. The polymerization of methyl acrylate was sensitive to UV light. Under UV light,the rate of polymerization is 8 times as high as the rate in dark.The overall activation energy was decreased by the UV light (313nm).A tentative explanation is given and the mechanism is discussed.

作者 Jian Hua DONG Jian Qing YANG Kun Yuan QIU Xin De FENG Department of Chemistry,Peking University,Beijing,100871

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第7期565-566,共2页 中国化学快报（英文版）

关键词 UV NM IV PHOTOSENSITIVITY OF CERIC ION INITIATED METHYL ACRYLATE POLYMERIZATION

分类号 O6 [理学—化学]

引文网络
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1董建华,杨建清,丘坤元,冯新德.PHOTOSENSITIVITY OF Ce (Ⅳ) INITIATED METHYL ACRYLATE POLYMERIZATION[J].Chinese Journal of Polymer Science,1992,10(2):169-175.
2董建华,丘坤元,冯新德.PHOTOSENSITIVITY OF CERIC ION INITIATED ACRYLAMIDE POLYMERIZATION[J].Chinese Journal of Polymer Science,1992,10(2):164-168.
3房江华,章哲彦,黄峥峥.Polymerization of Methyl Acrylate with Nd-Al-α,α'-Dipyridyl Catalyst System[J].Journal of Rare Earths,2001,19(4):308-310.
4陈纯福,孙君坦,李弘,何炳林.STUDIES ON THE HYDROGENATION OF METHYL ACRYLATE CATALYZED BY Pd/DVB CROSSLINKED POLY-(N-VINYL PYRROLIDONE)[J].Chinese Journal of Polymer Science,1990,8(4):295-301.
5ZOU Bo,JIANG HuanFeng College of Chemistry,South China University of Technology,Guangzhou 510640,China.PdCl_2-catalyzed heterocyclotrimerization in MeOH/scCO_2:A versatile approach to dimethyl pyridine-3,5-dicarboxylate from methyl acrylate and urea[J].Science China Chemistry,2008,51(5):447-451.
6Guo Yu YANG,Qing Min WANG,Jie ZHANG,Lian Xiang YU,Xi Zhang CAO (Department of Chemistry,Jilin University, Changchun 130023).A　NEW　METHOD　OF　JUDGING　THE　PHOTOSENSITIVITY　OF　WATER－SOLUBLE　PORPHYRINS　IN　THE　PHOTOSENSITIVE　SYSTEM[J].Chinese Chemical Letters,1995,6(5):433-436.
7(Jian Hua DONG,Da Hui LIU,Kun Yuan QIU,Xin De FANG (Department of Chemistry, Peking University, Beijing 100871).RADICAL POLYMERIZATION OF VINYL MONOMER INITIATED BY CERIC ION/TARTARIC ACID[J].Chinese Chemical Letters,1994,5(6):523-526.
8冯新德,丘坤元.STUDIES ON THE REACTION MECHANISM OF CERIC SALT REDOX SYSTEMS[J].Chinese Science Bulletin,1966,24(9):399-402.
9吴锦远,张广照,杨超雄.MECHANISM FOR THE INITIATION OF ACRYLONITRILE POLYMERIZATION BY POLYPROPYLENE-BASED POLYAMIDOXIME-THIOUREA COMBINATION[J].Chinese Journal of Polymer Science,1992,10(1):61-69.
10DING Youjun and QI Daquan (De partment of Chemistry, Pekinng University, Beijing).ESTIMATION OF REACTIVITY RATIOS OF METHYL ACRYLATE WITH N-ARYLMETHACRYL-AMIDE COPOLYMERS BY ~1H NMR METHOD[J].Chinese Journal of Polymer Science,1990,8(1):10-16.

Chinese Chemical Letters

1991年第7期

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