摘要
PASCA, ESR and Microreactor, have been used to study the states and properties of coking deposits on catalyst. The results indicate that the C exists as three types of states on catalyst surface. The first and second types of carbon are the main reason of the catalyst deactivation, but the third type has a promoting role in n-C_7 hydrocracking reaction. The S_s-C interacts strongly with catalyst, forming metal-carbon-support interaction (MCSI).
PASCA, ESR and Microreactor, have been used to study the states and properties of coking deposits on catalyst. The results indicate that the C exists as three types of states on catalyst surface. The first and second types of carbon are the main reason of the catalyst deactivation, but the third type has a promoting role in n-C_7 hydrocracking reaction. The S_s-C interacts strongly with catalyst, forming metal-carbon-support interaction (MCSI).