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Studies on the Preparation of Lanthanum-Copper Alloy by Molten Salt Electrolysis

Studies on the Preparation of Lanthanum-Copper Alloy by Molten Salt Electrolysis
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摘要 The electrochemical behaviour of copper electrode in molten NaCl-KCl-LaCl_3 has been investigated.The La-Cu alloy is formed at first and then the metallic lanthanum is deposited when the La^(3+)is reduced on the copper electrode.The technological conditions of preparing La-Cu alloy by consumable cathode have been dis- cussed.The La-Cu alloy contained lanthanum over 90wt% was obtained.The composition of alloy was LaCu_2 and La.The current efficiency was 85% and the recovery of lanthanum was near 90%. The electrochemical behaviour of copper electrode in molten NaCl-KCl-LaCl_3 has been investigated.The La-Cu alloy is formed at first and then the metallic lanthanum is deposited when the La^(3+)is reduced on the copper electrode.The technological conditions of preparing La-Cu alloy by consumable cathode have been dis- cussed.The La-Cu alloy contained lanthanum over 90wt% was obtained.The composition of alloy was LaCu_2 and La.The current efficiency was 85% and the recovery of lanthanum was near 90%.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 1991年第3期173-176,共4页 稀土学报(英文版)
关键词 Lanthanum-copper alloy Molten salt ELECTROLYSIS PREPARATION Lanthanum-copper alloy Molten salt Electrolysis Preparation
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