摘要
本文根据热动力学的基础理论,应用一级反应的无量纲参数法的基本方程,测定了26.6℃和30.4℃下甲酰苯胺在二(口恶)烷-水混合溶剂中碱性水解的热谱曲线,计算了所测反应的动力学参数—速度常数;计算了反应的活化能.活化自由能及活化熵等热力学性质.
On the basic theory of thermokinetic,applied fundamental equations of the method of dimensionless parameter for first or- der reaction in the paper,and the thermographic curve of the formarilide alkaline hydrolysis are measured in dioxane-water mixed solvent at 26.6 and 30.4℃.The kinetic parameter of meusured reaction—the rate constant,activation energies and the thermodynamic properties of the activation free-energies and activation entropies etc of the reaction are also calculated.
出处
《四川师范大学学报（自然科学版）》
CAS
CSCD
1991年第3期77-80,共4页
Journal of Sichuan Normal University（Natural Science）
关键词
碱性水解
热谱曲线
活化
无量纲
alkaline hydrolysis
thermographic curve
activation
dimensionliss
