摘要
本文采用水-有机溶剂合成了三个稀土硝酸盐与邻菲罗啉的混配配合物,通过元素分析、红外、差示扫描和热重等分析测试手段,确证了配合物的组成为Ln(Phcn)_4(NO_3)_3·3H_2O,并研究了它们的性质。
In this paper we syntheize three complexes of light rare earth with Phen and the nitrate from aqueous organic solvents. The composition of three complexes is Ln (Phen)_4(NO_3)_3· 3H_3O as characterised by elementary analysis, infrared spectra, DSC and thermogravimetric (TG) analysis.
出处
《化学研究与应用》
CAS
CSCD
1991年第3期42-46,共5页
Chemical Research and Application
关键词
轻稀土
邻菲罗啉
配合物
高配比
light rare earth
1, 10-Phenanthro line
complex compound
high coordinate ratio
