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Constraint of Isomorphous Substitution in Magnetite on Its Catalytic Activity in Heterogeneous Fenton Reaction

Constraint of Isomorphous Substitution in Magnetite on Its Catalytic Activity in Heterogeneous Fenton Reaction
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摘要 In nature, iron cations in magnetite are usually isomorphically substituted by divalent (Co, Ni, Zn, Cu, Mn, etc.), trivalent (Al, V, Cr, etc.) and tetravalent (Ti) cations while maintaining the spinel structure. Some of the substituting cations, e.g. Cr3+, V3+ and Mn2+, improve the catalytic activity of magnetite in heterogeneous Fenton reaction through the enhancement of hydroxyl radical OH production and the pollutant adsorption. In nature, iron cations in magnetite are usually isomorphically substituted by divalent (Co, Ni, Zn, Cu, Mn, etc.), trivalent (Al, V, Cr, etc.) and tetravalent (Ti) cations while maintaining the spinel structure. Some of the substituting cations, e.g. Cr3+, V3+ and Mn2+, improve the catalytic activity of magnetite in heterogeneous Fenton reaction through the enhancement of hydroxyl radical OH production and the pollutant adsorption.
出处 《矿物学报》 CAS CSCD 北大核心 2013年第S1期51-51,共1页 Acta Mineralogica Sinica
关键词 MAGNETITE isomorphous SUBSTITUTION CATALYSE degradation magnetite isomorphous substitution catalyse degradation
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