摘要
由于大部分环境样品的浓度非常低,为了实现其直接检测,提出将一种集成化的微型富集器应用到色谱系统中。富集器可实现色谱系统的进样与样品富集,能将色谱仪的检测限提高1~2个数量级。设计的富集器采用了高容量4平行通道结构,沟道内填充了高吸附率的Tenax-TA吸附材料,来实现对环境样品中挥发性有机化合物组分的富集。此外,为了密闭热解吸过程中所释放的组分,在微型富集器后集成了微型阀。试验结果表明,研制的微型富集器取得了15倍以上的富集因子。而且,通过微阀的控制,色谱峰的拖尾和峰展宽得到了有效的控制。因此,该微型富集器可广泛应用到环境样品的快速检测中,提高各检测器对复杂环境的适应能力。
The concentration of most environmental samples is very low.In order to directly detect these samples,an integrated micro pre-concentrator,which can significantly improve detection limit of mini gas chromatography system with 1-2orders,is developed.The micro pre-concentrator has 4parallel channels filled with enough Tenax-TA as adsorbent materials for concentrating volatile organic compounds.For closing the released components during thermal desorption process,a micro-valve is integrated behind the pre-concentrator.The result demonstrates the proposed pre-concentrator can effectively concentrate components with a concentration factor of 15.Moreover,the chromatography peak broadening is greatly compressed under controlling by the microvalve.Therefore,the micro-fabricated pre-concentrator can be easy to deploy and suitable for a number of applications involving on-site monitoring of environmental samples.
出处
《强激光与粒子束》
EI
CAS
CSCD
北大核心
2015年第2期131-135,共5页
High Power Laser and Particle Beams
基金
supported by National Natural Science Foundation of China(61176112,60976088)
Beijing Science and Technology Plan Project(Z141100003414003)
关键词
微型富集器
富集因子
微型色谱系统
检出限
micro pre-concentrator
concentration factor
mini-gas chromatography system
detection limit
