摘要
报道了一个新型草酸根桥联双核铜( )配合物[Cu2(L)2(μ-ox)](ClO4)2(1)(L=1,5,9-三氮环十二烷)的制备、表征、光谱和磁性质.配合物1中的2个铜离子之间存在非常强的反铁磁耦合作用(2J=-454cm-1).
The preparation and characterization of a new oxalato-bridged dinuclear Cu~Ⅱ complex, [Cu_2(L)_2(μ-ox)](ClO_4)_2 (1), where L=1,5,9-triazacyclododecane, together with its spectral and magnetic properties are reported. The magnetic susceptibility of 1 indicates a very strong anti-ferromagnetic coupling with 2J=-454 cm^(-1). The strength of the exchange interaction is discussed in detail.
出处
《天津师范大学学报（自然科学版）》
CAS
2004年第2期16-19,共4页
Journal of Tianjin Normal University：Natural Science Edition
基金
F inancial Support from the Natural Science Funds of Tianjin( Xiao-jun Zhao
3 -2 5 -2 0 0 4)
