期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

六硝基六氮杂异伍兹烷制备工艺研究开发新进展 被引量：15

RESEARCHE AND DEVELOPMENT OF HNIW SYNTHESIS
下载PDF
导出
摘要 六硝基六氮杂异伍兹烷 (HNIW )是一种能量密度很高的新型含能化合物 ,具有广阔使用前景。本文对其制备工艺路线进行了综述。根据工艺安全、产品纯度和制备成本对合成六硝基六氮杂异伍兹烷三种常用硝化前体 :四乙酰基二苄基六氮杂异伍兹烷 (TADB)、四乙酰基二甲酰基六氮杂异伍兹烷 (TADF)和四乙酰基六氮杂异伍兹烷 (TAIW ) Hexanitrohexaazaisowurtzitane(HNIW), is a compound of high energy density having a variety of applications in prospect. The routes of synthesis in its preparation were reviewed. Three nitrolysable precursors to HNIW, including tetraacetyldibenzylhexaazaisowurtzitane(TADB),tetraacetyldiformyllhexaazaisowurtzi-tane(TADF) and tetraacetylhexaazaisowurtzitane(TAIW) were discussed emphatically in terms of their process safety, product purity and costs of production.
作者 赵信岐 方涛 孙成辉
机构地区 北京理工大学材料科学与工程学院
出处 《兵工学报》 EI CAS CSCD 北大核心 2004年第3期354-358,共5页 Acta Armamentarii
关键词 六硝基六氮杂异伍兹烷 制备工艺 含能化合物 产品纯度 高能量密度材料 合成 material synthesis and technology, Hexanitrohexaazaisowurtzitane(HNIW), high energy density material, synthesis
分类号 TQ564 [化学工程—炸药化工]
  • 相关文献

参考文献23

  • 1Nielsen A T, Nissan R A, Vanderah D J . Formation of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracy[5.5.0.05,9.03,11]dodecanes from glyoxal and benzylmines. J Org Chem, 1990,55:1459-1466
  • 2Nielsen A T, Calif S B. Caged polynitramine compound. US 5693794, 1997.
  • 3Hamilton R S, Sanderson A J, Wardle R B. Studies of the synthesis and crystallization of HNIW. In: Proc of 31st International Annual Conference of ICT.2000. 21-1-21-9
  • 4Cannizzo L, Hamilton S, Sanderson A . Development of an alternate process for the synthesis of HNIW. In: Proc of 32nd International Annual Conference of ICT.2001, 108-1-108-9
  • 5Latypov N V, Wellmar U, Goede P. Synthesis and scale-up of HNIW from hexabenzylhexaazaiwso wurtzitane. Organic Process Research and Development, 2000.4:156-158
  • 6Wardle R B, Edwards W. Improved hydrogenolysis of 2,4,6,8,10,12- hexabenzyl-2,4,6,8,10,12-Hexaazatetracyclo [5.5.05,9.03,11]dodecane. WO 20785, 1997.
  • 7Wardle R B, Hinshaw J C, Braithwaite P B. Sythesis of caged nitramine HNIW(HNIW). In: Proc of 27th International Annual Conference of ICT. 1996,27-1-27-10
  • 8Bazaki H, Kawabe S, Miya H. Synthesis and sensitivity of HNIW. Propellants, Explosives, Pyrotechnics, 1998,23:333-336
  • 9Duddu R G,Dave P R. Process and compositions for nitration of N-substituted isowuetzitane compounds with concentrated nitric acid at elevated temperatures to form HNIW and recovery of gamma HNIW with high yields and purities. US 6015898, 2000.
  • 10Surapaneni R, Damavarapu R, Duddu R . Process improvements in HNIW manufecture. In:Proc of 30th International Annual Conference of the ICT. 1999.108-1-108-4

二级参考文献27

  • 1白军红,冯泽旺,赵信岐.CL-20及其类似物的质谱裂解途径[J].火炸药学报,2000,23(4):61-62. 被引量：1
  • 2赵信岐,施倪承.ε-六硝基六氮杂异伍兹烷的晶体结构[J].科学通报,1995,40(23):2158-2160. 被引量：34
  • 3北京理工大学CL－20合成课题组.高能量密度材料CL－20合成成功.八六三计划高技术新材料快报[M].,1994,167(8)..
  • 4陈福波 段宝如 等.兵器工业部214所研究报告汇编（1978-1980）[M].,1983.29.
  • 5管晓培.笼形化合物的合成研究[M].北京理工大学,1993,10..
  • 6赵信歧 施倪承.-[J].科学通报,1996,41(7):574-576.
  • 7[3]M Kaiser, et al. Characterization of impurities in CL-20 by NMR spectroscopy [A]. Proceedings of 30th Intenational conference of ICT[C]. 1999.94-1.
  • 8Simpson R L,Urtiew P A,Ornellas D L.CL-20 performance exceeds that of HMX and its sensitivity is moderate,Propellants,Explos,Pyoth,1997,22:249～255
  • 9Hamilton R S,Sanderson A J,Wadle R B.Studied of the synthesis and crystallization of CL-20.In:Proc of 21th International Annual Conference of ICT.Karlsruhe:2000.21-1～21-9
  • 10赵信岐 刘娟.一乙酰基五硝基六氮杂异伍兹烷结构表征[J].科学通报,1997,42(7):984-984.

共引文献75

同被引文献101

引证文献15

二级引证文献30

兵工学报
2004年 第3期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部