摘要
制备了掺有稀土发光材料的高折射率玻璃微球,并用XRD、Raman等进行了表征。实验结果表明,该玻璃微球粒径分布范围窄,光学性能好,其折射率约为1.93。用改造的显微拉曼光谱仪测量了微球上转换发光光谱,在其荧光光谱上发现了很强的形貌共振,并用光学微腔理论进行了解释。
High refractive index glass microspheres doped with Nd2O3 were prepared by melting down the powder of the mixture of the desired composition in a gas burner. The glass microspheres were characterized by power X-ray diffraction (XRD) and Raman spectrum. It was found that the uniformity of the component in the glass microsphere was good. The refractive index of glass was about 1.93. The strong morphology dependent resonances of the luminescence in the microsphere were observed. Based on the Mie scattering theory, the phenomenon was explained.
出处
《功能材料》
EI
CAS
CSCD
北大核心
2004年第4期483-484,共2页
Journal of Functional Materials
基金
国家自然科学基金资助项目(60178024)
北京工业大学博士启动基金资助项目(KZ0606200372)
关键词
高折射率玻璃
玻璃微球
稀土发光
光学微腔
Gas burners
Light scattering
Luminescence of solids
Neodymium compounds
Raman spectroscopy
Refractive index
Resonance
X ray diffraction analysis