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Preparation of Macroporous Poly (vinyl alcohol-co-triallyl isocyanurate) Beads Bearing Aminocarboxylic Acid as Functional Groups by Suspension Polymerization

Preparation of Macroporous Poly (vinyl alcohol-co-triallyl isocyanurate) Beads Bearing Aminocarboxylic Acid as Functional Groups by Suspension Polymerization
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摘要 Macroporous poly (vinyl acetate-co-triallyl isocyanurate) beads were prepared with suspension polymerization method. The copolymer beads were then transformed into poly (vinyl alcohol-co-triallyl isocyanurate) by ester exchange reaction. Aminocarboxylic acids were immobilized on the copolymer beads by the esterification of hydroxyl groups with diethyl-lenetriaminepentaacetic bisanhydride. The weak acid exchange capacities, specific surface areas and mean pore diameters of the resultant resin beads were measured. Macroporous poly (vinyl acetate-co-triallyl isocyanurate) beads were prepared with suspension polymerization method. The copolymer beads were then transformed into poly (vinyl alcohol-co-triallyl isocyanurate) by ester exchange reaction. Aminocarboxylic acids were immobilized on the copolymer beads by the esterification of hydroxyl groups with diethyl-lenetriaminepentaacetic bisanhydride. The weak acid exchange capacities, specific surface areas and mean pore diameters of the resultant resin beads were measured.
作者 Hai Tao LI Ke Yu SHI
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第3期267-269,共3页 中国化学快报(英文版)
基金 This work was supported by the National 973 project (G1999064707)
关键词 Macroporous adsorption resin suspension polymerization poly (vinyl alcohol-co-triallyl isocyanurate) aminocarboxylic acid. Macroporous adsorption resin, suspension polymerization, poly (vinyl alcohol-co-triallyl isocyanurate), aminocarboxylic acid.
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参考文献2

  • 1K.Thies,S.A.Prigent,et al. Artificial Organs . 1988
  • 2B.Fang,T.Q.Jiang,J.EastChinaUniv. Sci. andTech . 1998

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