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宏观分子自组装:一条架在分子和结构体之间的桥梁

Macroscopic molecular self-assembly:a bridge between molecules and macroscopic objects
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摘要 文章介绍了一种新的分子自组装现象 :宏观分子自组装 .由一种新型的两亲性超支化多臂共聚物在丙酮中直接自组装形成厘米长度、毫米直径的宏观多壁螺旋管 .并对宏观管子的精细结构、性能进行了详细描述 ,同时阐述了宏观分子自组装机理 .宏观分子自组装现象的发现将分子自组装的研究领域推进到了宏观尺度范围 . Macroscopic molecular self-assembly from an amphiphilic hyperbranched multi-arm copolymer is reported. Multi-wall helical tubes with diameters and lengths of the order of mm and cm, respectively, have been produced by macroscopic molecular self-assembly, and their morphology, properties and self-assembly mechanism studied in detail. This development of molecular self-assembly on the macroscopic scale is a significant step forward.
出处 《物理》 CAS 北大核心 2004年第7期469-472,共4页 Physics
基金 国家自然科学基金(批准号 5 0 2 3 3 0 3 0 2 0 2 740 2 4 2 0 3 0 40 0 7)资助项目
关键词 宏观分子自组装 螺旋管 超支化 不规则 分子间作用力 macroscopic molecular self-assembly,helical tubes, hyperbranched, ill-defined
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