摘要
系统总结了Ni、Pd、Pt、Rh、Cu等过渡金属配合物催化活化Si-C、Sn-C、S-C、Se-C、Cl-C、Br-C等杂原子-碳键及其与炔烃的加成反应.这些新型的炔烃加成反应提供了合成含R3Si、R3Sn、RS、RSe、Cl和Br等活性官能团烯烃化合物的原子经济型一步合成方法.同时加成反应体系具有很高的立体选择性和区域选择性.
This paper reviews the transition me tal complexes such as Ni,Pd,Pt,Rh,C u-catalyzed activation of hetero -carbon bonds and the related catalytic addition reactions with a lkynes.These new addition reactions pro-vide one-step,atom-economic methods for the preparation of the functio nalized alkenes which have R 3 Si,R 3 Sn,RS,RSe,Cl and Br groups.The additio n reactions proceed with high stereo selectivities and regioselectivit ies.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
2004年第F08期989-994,共6页
Acta Physico-Chimica Sinica
关键词
过渡金属配合物
杂原子-碳键
活化
加成反应
选择性
Transition metal complex,Hetero -Carbon bond,Activation,Addition r eaction,Selectivity