有机磷化合物的质谱研究 Ⅻ.二氮磷杂环戊烷化合物的开环断裂和重排反应

Mass Spectrometric Study on Organo-phosphorus Compounds——Ⅻ. The Ring Opening and Rearrangement Reactions of Diazaphospholidines

用EI质谱和联动扫描技术以及精确质量测量技术研究了11个新合成的含磷杂环化合物,主要讨论了分子离子的开环断裂反应和骨架重排,H-重排以及苯基重排等各种重排反应。

By EI mass spectrography, link-scaning and accurate mass measuring technique, 11 newlysynthesized organo-phosphorus compounds, diazaphospholidines, were studied. Their ring-openingreactions and rearrangement reactions including skeleton rearrangement, H-rearrangement andphenyl rearrangement were discussed in detail.