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PF/PnBA IPN的合成及相容性研究 被引量:2

A STUDY ON THE SYNTHESIS AND THE COMPATIBILITY OF PHENOLIC/POLY (N-BUTYL ACRYLATE) IPN' S
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摘要 本文采用乳液和溶液聚合法合成PF/PnBA IPN,并对产物进行了动态力学性能、热重分析及微观形态研究。结果表明,IPN可使组分相容性得到提高热性能得以改善,乳液聚合与溶液聚合法合成IPN产物的微观形态有所不同。 The PF/PnBA IPN were prepared by emulsion and solution polymerization,and the compatibility of the components in the IPN' s was studied with the help of DMA, TEM, TG. The results showed that the methods of synthesis of the PF/PnBA IPN were available. For the emulsion polymerization IPN, the compatibility of the two components was improved when PF/PnBA was equal to 30/70. For the solution polymerization IPN, the compatibility of the system was better when PF/PnBA was equal to 60/40. The thermal stability of this composition IPN was better. The TEM showed that the microstructure of the emulsion polymerization IPN was different from that of the solution polymerization IPN.
机构地区 辽宁大学化学系
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 1993年第2期33-37,共5页 Polymer Materials Science & Engineering
关键词 酚醛树脂 聚丙烯酸丁酯 互穿网络 phenolic resin, poly (n-butyl acrylate), IPN.
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  • 1常怀春 李冠军.酚醛泡沫塑料的制备方法[P].中国专利:1085576.1994—04—20.
  • 2KurodaA.OnishiM.Phenolic Resin Foam and Process for Producing the Same[P].欧洲专利:105576.1983—07—13.
  • 3NakarnuraT KashimaK.Manufacture of Phenolic Urethane Fhms Free of Surface Brittleness[P].日本专利:63213512.1988—09—06.
  • 4Kuroda A , Onishi M. Phenolic resin foam and process for producing the same[P],欧洲专利 : 105576,1983 - 07 -13.
  • 5Nakamura T, Kashima K. Manufacture of phenolic urethane foams free of surface brittleness [ P]. 日本专利 :63213512,1988 - 09 - 06.
  • 6梁明莉,金关泰,祝军,程珏.聚氨酯改性酚醛泡沫塑料[J].北京化工大学学报(自然科学版),2002,29(1):47-50. 被引量:28

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