[(Et_4N)_1.5{Li(H_2O)_6}0.5][Cd_2(SC_6H_4Bu^t-4)_6]·C_2H_5OH双核镉配合物的合成与晶体结构

Synthesis and Crystal Structure of [Et_4N)_(1.5){Li(H_2O)_6}_(0.5)] [Cd_2(SC_6H_4Bu^t-4)_6] · EtOH

标题化合物由4-Bu'S_6H_4SLi、Cd(NO_3)2·4H_2O和Et.NBr反应制备。用X射线单晶衍射法测定其晶体结构。

The title complex was synthesized and structurally characterized. The crystal belongs to the space group C2/c, α= 5.727(3) nm, 6= 1.2059(3) nm, c=2. 5245(16) nm, β=101.39(5)°, V = 17. 0921(5) nm3, Dc=l. 178 g/cm, Z=8, R=0. 076 for 4692 unique reflections [F≥4. 0σ (F)]. The cadmium is tetrahedral coordination with two terminal and two bridging ligands. The central M2S2 ring is planar and approximately rectangular.