应用不同交联度的聚合物Wittig试剂合成亚洲玉米螟性信息素

Synthesis of Insect Sex Pheromone of Asian Corn Borer with Various Link Polymeric Wittig Reagents

我国广东省测试分析中心及美国的Klun几乎同时确定亚洲玉米螟性信息素的化学结构为(E)及(Z)-12-十四碳烯-1-醇乙酸酯(Z:E=1:1)。合成方法大多由合适的炔烃出发,先合成相应的炔键类似物,再转化成烯键,但原料较难获得,反应条件苛刻。

Insect sex pheromone of Asian Corn Borer was synthesized by the reaction between various link polymeric Wittig Reagents and self made 12-bromo-dodecanol.A discussion on the capacity of functional group and the effect on the reaction was included.