三元共聚反应序列分布的Monte Carlo模拟

Monte Carlo Simulation of Sequence Distributions of Terpolymerization

本文利用Monte Carlo模拟获得了不同分子链长度的三元共聚反应产物[聚(苯乙烯-醋酸乙烯酯-马来酸酐)]的序列分布,我们发现三聚物的序列分布可以通过在反应过程中滴加活泼反应单体(本文中的苯乙烯)来加以控制。

In this paper, we use Monte Carlo method to obtain the sequence distributions of terpolymerization products (polystyrene/vinyl acetate/maleic anhydride) with various molecular chain length. We find that sequence distribution of the terpolymer can be controlled by the method of titrating the more. reactive monomer (e.g. styrene in this paper) during the polymerization procedure.