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金属催化和生物催化在对映体拆分中的联合应用 被引量：1

Combined Application of Metal Catalysis and Bio-Catalysis in Enantiomer Resolution Process
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摘要 随着对单一对映体化合物需求的日益增长 ,外消旋体向单一对映体的转化 (去外消旋化过程 )成为研究的主要方面之一 ,最近在去外消旋化过程中的生物催化和金属催化的联合作用被证明是非常有效的。 Since there is a great increase of demand of enantiopure compounds, the transformation of recemate into single stereoisomer is one of the most important area of research. The recent development of the combined application of enzyme and metal catalysis has been proved an effective deracemized process. Dynamic kinetic resolution and cyclic deracemization processes have been shown particular promotion in this area.
作者 王述彬 刘均洪
机构地区 青岛科技大学化工学院
出处 《河南化工》 CAS 2004年第8期1-3,共3页 Henan Chemical Industry
基金 国家自然科学基金资助课题 ( 2 0 1760 19)
关键词 金属催化 生物催化 对映体拆分 循环去外消旋化 metal catalysis biocatalysis enantiomer resolution cyclic deracemization
分类号 Q556 [生物学—生物化学]
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参考文献12

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二级参考文献2

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共引文献1

同被引文献17

  • 1张占辉,刘庆彬.酶-过渡金属配合物催化的动态动力学拆分研究进展[J].有机化学,2005,25(7):780-787. 被引量：12
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  • 6CHOI Y K,KIM M J.Lipase/palladium-catalyzed asymmetric transformations of ketoximes to optically active amines[J].Org Lett,2001,3(25):4099-4101.
  • 7PARVULESCU A N,JACOBS P A,DEVOS D E.Palladium catalysts on alkaline-earth supports for racemization and dynamic kinetic resolution of benzylic amines[J].Chemistry,2007,13 (7):2034-2043.
  • 8PARVULESCU A N,JACOBS P A.Microwave-promoted racemization and dynamic kinetic resolution of chiral amines over Pd on alkaline earth supports and lipases[J].J Catal,2008,255(2):206-212.
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  • 10PARVULESCU A N,JACOBS P A.Support influences in the Pd-catalyzed racemization and dynamic kinetic resolution of chiral benzylic amines[J].Appl Catal A:Gen,2009,368(1/2):9-16.

引证文献1

河南化工
2004年 第8期

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