摘要
给出用电化学反应和加成反应合成水溶性多羟基富勒烯衍生物褐色晶体的方法.通过研究分析其红外吸收谱、快原子轰击电离质谱和1H及13C核磁共振谱,发现该衍生物为富勒醇.该衍生物能在水中及空气中长时间稳定存在,在25℃下在水中的溶解度大于100mg/mL.
A method is presented for synthesizing water-soluble brown crystalline grain of multi-hydroxylate fullerite by means of two different methodselectrochemistry and additive reaction.It is found by FTIR,FABMS,(~1H)-NMR and ^(13)C-NMR spectra that the water-soluble fullerite is multi-hydroxylate fullerite.It is able to exist in water or air for a long time and its solubility in water is more than 100 mg/mL at 25 ℃.
出处
《兰州理工大学学报》
CAS
北大核心
2004年第4期70-72,共3页
Journal of Lanzhou University of Technology
基金
甘肃省自然科学基金(YS 011 A22 010)
甘肃省科技攻关项目(GS022 B52 113)
