摘要
介绍了原子转移自由基聚合方法ATRP(atomtransferradicalpolymerization)的机理.综述了ATRP的研究进展,包括采用的各种引发体系、反相ATRP技术、反应条件及其在高分子设计中的应用.通过原子转移自由基聚合可以方便地合成各种结构的模型聚合物,包括嵌段、接枝、星形及超支化共聚物等.
This review article introduced the mechanism of Atom Transfer Radical Polymerization (ATRP), and systemically summarized the important advance in ATRP, including various initiating systems, reverse ATRP, reaction condition and the application in macromolecule design. The technique of ATRP has been used to synthesize the model polymer with various structure, block copolymer, graft copolymer, star-shaped polymer and hyperbranched polymer.
出处
《华北工学院学报》
2004年第4期271-276,共6页
Journal of North China Institute of Technology
基金
山西省自然基金资助项目
