水杨醛硫代卡巴腙及其Ni(Ⅱ)、Zn(Ⅱ)配合物的合成与表征

Synthesis and characterization of a new thiocarbohydrazone and its complexes of Ni(Ⅱ),Zn(Ⅱ)

合成了水杨醛硫代卡巴腙配体及其金属镍、锌的配合物,所得化合物分别用元素分析、红外光谱、摩尔电导和电子光谱进行了表征,同时对配体进行了核磁共振氢谱和质谱表征,给出了化合物可能的结构.

A new thiocarbohydrazone ligand derived from thiocarbohydrazide with salicylaldehye and its metal Ni(Ⅱ) and Zn(Ⅱ) complexes have been synthesized and characterized by elemental analyse, IR, conductivity and clectronic spectra. The ligand was characterized by ~1H NMR spectra and mass spectrum. The coordinate mode of the ligand and the possible structures of the compounds were also proposed.