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我国产出的鳞镁铬矿-鳞镁铁矿系列的过渡矿物——铬鳞镁铁矿 被引量:1

CHROM-PYROAURITE, Mg_6(Fe^(3+),Cr)_2CO_3(OH)_(16)·4H_2O,A NEW VARIETY ON THE PYROAURITE-STICHITITE JOIN
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摘要 Chrom-pyroaurite, associated with serpentine, chromite, magnetite, ehaleopyrite,pyrite and etc., is found in serpentinite in Southwestern China. Its coiour is violet in aggregate, but colorless or pale pink in thin fragments. The mineral is transparent with glassy luster. Specific gravity 2.12±0.01 (determined by s.g. bottle).Hardness 1--1.5. It occurs in massive aggregate and is of apparent greasy feel. Under microscope it has scaly and fibrous appearance. Pleochroism is not clear with N.--colorless, No--pale pink. Uniaxial negative. No = 1.5560, N, = 1.5450, No -- N4=0.011. Apparent endothermic peaks are noticed at 270° and 460℃ respectively.Chemical composition is gaven as: MgO 36.74, 35.62; FeO 0.1, 0.15; MuO 0.06, 0.01;Fe2O3 13.54, 12.79; Cr2O3 6.94, 7.49; Al2O3 2.21, 1.74; CO2 6.45, 7.78; H2O^+ 32.33, 32.30;H2O^- 2.38, 1.78; total 100.75, 100.56. The mineral belongs to trigonal system, α0=6.165A, c0= 46.760A, c0/α0 = 7.585. Cell dimension V= 1537A^3, Z = 3. Strongest Xray pattern lines are 10.48(8), 8.56(5), 7.8(10), 5.12(4), 3.89(10), 2.60(5), 1.99(6).The mineral is named after its eomposition. Chrom-pyroaurite, associated with serpentine, chromite, magnetite, chalcopyrite,pyrite and etc., is found in serpentinite in Southwestern China. Its colour is violet inaggregate, but colorless or pale pink in thin fragments. The mineral is transparentwith glassy luster. Specific gravity 2.12 ± 0.01 (determined by s.g. bottle). Hardness1--1.5. It occurs in massive aggregate and is of apparent greasy feel. Undermicroscope it has scaly and fibrous appearance. Pleochroism is not clear with N_o——colorless, N_e——pale pink. Uniaxial negative. N_o = 1.5560, N_e = 1.5450, N_o - N_e =0.011. Apparent endothermic peaks are noticed at 270° and 460℃ respectively.Chemical composition is gaven as: MgO 36.74, 35.62; FeO 0.1, 0.15; MnO 0.06, 0.01;Fe_2O_3 13.54, 12.79; Cr_2O_3 6.94, 7.49; Al_2O_3 2.21, 1.74; CO_2 6.45, 7.78; H_2O^+ 32.33, 32.30;H_2O^- 2.38, 1.78; total 100.75, 100.56. The mineral belongs to trigonal system. α_0 =6.165 A, c_0 = 46.760 A, c_0/α_0 = 7.585. Cell dimension V = 1537 A^3, Z = 3. Strongest X-ray pattern lines are 10.48(8), 8.56(5), 7.8(10), 5.12(4), 3.89(10), 2.60(5), 1.99(6).The mineral is named after its composition.
出处 《地球化学》 CAS 1978年第4期281-290,320,共11页 Geochimica
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  • 1江绍英,张光荣,梁惠娥,等.我国水滑石的发现及其矿物学特征[J].矿物学报,1984(4):296-302.
  • 2Bruun Hansen H C, Koch C B. Synthesis and characteriza- tion of pyroaurite[J]. Applied clay science, 1995, 10(1) : 5 --19.
  • 3Frost R L, Erickson K L. Vibrational spectroscopy of stich- tite[J].. Spectrochimica Acta Part A: Molecular and Biomo- lecular Spectroscopy, 2004, 60(13): 3001--3005.
  • 4Frost R L, Adebajo M O, Erickson K L. Raman spectrosco- py of synthetic and natural iowaiteFJ3. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2005, 61 (4): 613--620.
  • 5柴超,汪立今.菱铁矿的拉曼光谱研究[J].西部探矿工程,2012,24(1):156-158. 被引量:1

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