溶液中二级反应动力学电导测定新方程的研究

STUDIES ON THE NEW EQUATIONS OF THE METHOD OF ELECTRIC CONDUCTANCE DETERMINATION OF KINETICS OF SECOND ORDER REACTION. IN SOLUTION

研究电导法测定溶液中二级反应速率常数k的计算方程。无论是对等浓度反应还是不等浓度反应,引入等时间差△t均可得到不需测定L_0和L_∞的新方程。对乙酸乙酯皂化反应处理结果与文献值吻合。

In this paper, the equations of the method of electric conductance determination of kinetics of second order reaction in solution were studied. 'For both equal and unequal concentration reactions, using isochronal differences can obtain the new equations with which do not need to determine L0 and L∞. The results of experiments of saponification of acetic ether are consistent with those in literature.