摘要
以亚硫酰氯为试剂和溶剂合成了8个手性α-溴代酸酯,其中两个是新化合物。与传统方法相比,不需使用红磷,反应条件温和、操作简便、产率高且几乎全为α-—溴代产物。
Eight chiral a-bromo-carboxylic esters were synthesized by using thionyl chloride as a solvent and a reagent, two of them are new compounds. Compared with traditional methods, it needn't red phosphorous and easy to operate. The yields were excellent and the products almost were α-monobrominated products.
出处
《广西师范大学学报（自然科学版）》
CAS
1993年第2期54-57,共4页
Journal of Guangxi Normal University:Natural Science Edition
基金
国家自然科学基金资助课题
关键词
α-溴代酸酯
亚硫酰氯
手性化合物
(-)-menthol
(-)-borneol
α-bromo-carboxylic esters
thionyl chloride
