三氟甲基苯胺的合成与应用被引量：4

下载PDF

导出

摘要三氟甲基苯胺是重要的医药、农药和染料中间体,本文介绍了其生产方法与应用,其中重点介绍合成工艺技术进展及其下游产品应用。

作者秦伟程

机构地区中石化南京化工厂

出处《有机氟工业》 CAS 2004年第2期19-23,共5页 Organo-Fluorine Industry

参考文献18

1Klaube E, Braden R. Process for the trifluoromethyl - aniline[ P]. EP 39810 : 1981 - 1 - 22.
2Klaube E, Braden R. Process for the trifluoromethyl - aniline[ P]. DE 3017542 : 1980 - 11 - 10.
3BAYER AG. Process for the preparation of 2 - trifluoromethyl- aniline from 2 - trihalometyl anilinocarbonyl derivatives and hydrogen fluoride [ P]. GB955898,1964 - 06 - 15.
4Lin H C. 2 - (Trifluoromethyl)phenyl carbamic fluoride[P] ,1984 -08 -21.
5Kirk- Othmer ,Encyclopedia of Chemical Technology. 4^[th] ed. New York :John Wiley &Son Inc, 1997. ( 5 ) : 491, ( 7 ) :814.
6bl Freffelder ,et al. J Org Chem. [ J] 1961,26:1477 ～ 1480.
7A Arnold, et al . Preparation of 3 - tirfluoromethyl - aniline[ P]. GB2311753 : 1973 - 09 - 13.
8许丹倩,徐振元,陈静华,卜鲁周,韩经龙.高纯间三氟甲基苯胺开发[J].农药,2001,40(1):9-12. 被引量：19
9Albrecht M, Kahte B. Preparation of Trifluommethylanilenes[ P]. US 6333433:2001 - 12 - 25.
10Chen Q Y, Duan J X. Methyl - 3 - oxt-fluorosulfonylper fluoropentanoate; A ersatile trifluoromethylating agent for organic halides [J]. J. Chem. Soc,1993,13:1391.

1许丹倩.间三氟甲基苯胺综述[J].浙江化工,1996,27(1):10-12. 被引量：15
2化工部农药信息总站.国外农药品种手册[Z].,1996..
3Hisao U. and Takamasa F.. A novel and convenient method for trifluoromethyltion of Organic halides using CF3SiR/3 KF/Cu(Ⅰ)system. Tetre Lett. 1991,32(1):91～94
4Claude N. P., More T. S.. Process for perfluoroalkylation of aromatic derivatives. U. S 4731450 (1988)
5Terao U. and Sumi I.. Power- variable rifluoromethyl a ting agents, (Trifhio - romethyl)dibenzothio - and - phenium Salt system. Tetre Lett. 1990,31(25):3579
6Nobumasa K., Takesh O. ,Takarnasa F.. Diret Perfluoroalkylation of Aromatic and Heteroaromatic compounds with perfkeoroalkane supfonyl chlorides catalysed by a Ruthenium(Ⅲ) phosphoine complex. J. Chem Soc Perkin Trars I, 1994:1339
7Lennon H. M. , Michad J. R. J.. Method for converting carboxylic acid grops to trichloromethyl groups. US 4419514 (1983)
8Seiwell, Linda P. Preparation of p - aminobenzotifluoride(p).U. S 4096185 (1978)
9Aldrich, Catalog Handbook of Fine Chemicals(B). 1998～1999
10Ufa J.K.D.,ReinwholdG. W.. 1-Aryl-4-alkylthiopyrazol-5 - amine derivatives. US 4804675 (1989)

1HUANG, Wei-Yuan,ZHANG, Han-Zhong Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032.The reaction of perfluoroalkanesulfonyl halides Ⅷ. A mild method for introducing BrCF_2 group to organic molecules[J].Chinese Journal of Chemistry,1992,10(3):274-277. 被引量：3
2雷宏,朱红军,韩邦友,徐守林.三氟甲基苯的合成[J].精细化工,2004,21(8):639-640. 被引量：8
3刘怡,马建国,马宁,李华,张谦.液相催化加氢制备间三氟甲基苯胺[J].河南化工,2005,22(1):20-21. 被引量：2
4常瑛,蔡春.三氟甲基化反应的研究进展[J].精细石油化工,2005,22(2):46-51. 被引量：10
5常瑛,蔡春.三氟乙酸钠对卤代芳烃的三氟甲基化反应[J].精细化工,2005,22(4):311-313. 被引量：4
6成四喜,吴放军.新型吡唑类广谱杀虫剂fipronil的合成与应用[J].农药译丛,1995,17(1):18-21. 被引量：11
7刘海辉,杜晓华,陈静华,徐振元.邻三氟甲基苯胺的合成[J].农药,2005,44(10):464-465. 被引量：4
8陈献,乔旭,崔咪芬,张进平,汤吉海.三氟甲基化合物的合成[J].化工新型材料,2005,33(10):63-66. 被引量：4
9赵美法.对三氟甲基苯胺的合成与应用[J].精细化工原料及中间体,2006(1):24-27. 被引量：2
10潘向君,吕亮.2,6-二氯-4-三氟甲基苯胺制备新工艺[J].农药,2006,45(3):167-170. 被引量：5

1吴浩,戴洪玉,廖万鹏,吴凤,周志旭,黄筑艳.CF_(3)SO_(2)Na为氟源“一锅法”合成四个三氟甲基吡啶化合物[J].广州化学,2022,47(2):34-39.

有机氟工业

2004年第2期

内容加载中请稍等...