一种含二茂铁基的多枝状分子的合成、表征及其性质研究

Synthesis, Characterization and Electrochemical and Nonlinear Optical Properties of a Dendritic Molecule Containing Ferrocene Units

采用新的方法合成了一种二茂铁衍生物———均三(二茂铁乙烯基)苯,通过元素分析、红外光谱、核磁共振氢谱、质谱、紫外可见光谱等对其进行了表征。用循环伏安法对其电化学性质进行了初步研究,用Z鄄扫描技术测试了它的非线性光学性能。结果表明,该化合物具有良好的电化学及非线性光学性质。

A new synthetic method is designed for a ferrocenyl derivative, 1,3,5-tris(ferrocenylethenyl)benzene, which has been characterized by elemental analysis, IR, H-1 NMR and MS. Furthermore, its electrochemical properties have been investigated using cyclic voltammetry method. The two-photon absorption of the compound was measured using the Z-scan technique at 532 nm. The results indicate that the compound has good electrochemical properties and strong NLO effects.