摘要
室温下 ,通过双核配合物 [Cu(dppm) (NO3 ) ]2 (dppm =双二苯基膦甲烷 )与四苯基硼钠在甲醇和二氯甲烷混合溶剂中反应制备了三核铜 (Ⅰ )配合物 [Cu3 (dppm) 3 (NO3 ) (OH) ](NO3 ) ,经过红外光谱、热重分析、核磁和ES MS等现代分析手段表征了配合物的物理化学性质 。
The novel luminescent trinuclear copper(Ⅰ) complex [Cu 3(dppm) 3(NO 3)(OH)](NO 3) has been obtained by treating binuclear copper(Ⅰ) [Cu(dppm)(NO 3)] 2 with sodium tetraphenyl boron (dppm=Ph 2PCH 2PPh 2). The complex was characterized by physico chemical and spectroscopic methods. The title complex exhibits photoluminescence behavior at room temperature.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2004年第8期978-980,共3页
Spectroscopy and Spectral Analysis
基金
国家自然科学基金面上项目 (2 0 2 71 0 1 7)资助课题
