3-全氟烷基-4-乙氧羰基-5-甲氧基-6-亚三苯膦基-2,4-己二烯酸甲酯的水解反应及其产物的结构表征

HYDROLYSIS OF METHYL-4-CARBOETHOXY-3-PERFLUOROALKYL-5-METHOXY-6-(TRIPHENYLPHOSPHORANYLIDENE)HEXA-2, 4-DIENOATE AND STRUCTURE ELUCIDATION OF THE REACTION PRODUCTS

一类含 6个碳的长链叶立德在适当条件下进行水解反应,反应产物经~1H NMR、^(13)CNMR、IR、MS分析方法的分析,确证了结构。同时提出了水解反应的可能的反应机理。

Long chain phosphonic yelides were hydrolyzed under suitable conditions. The reaction products were studied by ~1H NMR, ^(13)C NMR, IR, MS and microanalysis. A possible mechanism of the hydrolysis reaction was proposed.