期刊文献+

硼酸三异丙酯合成方法的改进

An improved method for the synthesis of triisopropyl borate ester
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摘要 采用氢化钙作为脱水剂,以硼酐及异丙醇为原料合成了硼酸三异丙酯,该方法具有成本低、操作简便、条件温和、产率高的优点。 Triisopropyl borate was synthesized with high yield from 2 propanol and boron oxide by using calcium hydride as drying agent to remove resultant water.This procedure could also be utilized in the synthesis of other trialkoxyl borates.For further investigation or application of the title compound,the present paper provided a simple and convenient method.
出处 《化学试剂》 CAS CSCD 北大核心 2004年第4期233-233,236,共2页 Chemical Reagents
关键词 硼酸三异丙酯 合成 改进 氢氧化钙 硼酐 异丙醇 氢化钙 triisopropyl borate synthesis boron oxide
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参考文献2

  • 1Nazarenko,Nicholas,Seidel,et al.Process for the preparation of triarylborane[P].US:4076756,1978-02-28.
  • 2Cole T E,Quintanilla R,Rodewald S.A simple and convenient method for synthesizing trialkoxyboranes and trialkoxyboroxins using calcium hydride as a drying agent[J].Synth.React.Inorg.Met.-Org.Chem.,1990,20,55-63.

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