苯甲醛单缩二氨基硫脲Ti(Ⅳ)、Ni(Ⅱ)、Cu(Ⅱ)配合物的直接电化学合成

The Direct Electrochemical Synthesis of Ti(Ⅳ)、Ni(Ⅱ)、Cu(Ⅱ) Complexes of Mono(benzaldehyde)-thiosemicarbazone

在以苯甲醛单缩二氨基硫脲(HL)为配体的非水溶剂中,用Ti、Ni、Cu金属做阳极,用电化学金属阳极氧化法合成了苯甲醛单缩二氨基硫脲与Ti( )、Ni( )、Cu( )的金属配合物。通过元素分析、红外光谱、紫外光谱、磁化率、摩尔电导等对配体和配合物进行了表征。

Ti(Ⅳ), Ni(Ⅱ), Cu(Ⅱ) complexes of mono(benzaldehyde)-thiosemicarbazone(HL) were synthesized by the electrochemical oxidation of anodic metals such as Ti, Ni and Cu in non-aqueous solution containing ligand(HL). The complexes were characterized by elemental analysis, IR, UV, magnetic susceptibility, molar conductivity and etc.