三氟化硼催化合成烯丙基缩水甘油醚

<title>eparation of Ally Glycidyl Ether By the catalysis BF_3-Et_2O

采用三氟化硼乙醚络合物作为催化剂,用烯丙醇和环氧氯丙烷先进行加成反应,再环化成为烯丙基缩水甘油醚。 研究了催化剂用量、反应原料配比及碱用量对产物收率的影响。两步反应的总收率为80％左右。中间体和产物分别用光谱进行了 表征。

<abstract> the catalysis BF3-Et2O, the tide Compound has been synthesis from allyl alcohol and epichlorlhydrin after a series reaction included addition and cyclization. The effect of dosage of catalyst, epichlorohydrin and base on product yield are studied.