摘要
以Mn(Ⅲ)/Mn(Ⅱ)为间接氧化还原体系,用间接电氧化的方法,在相转移催化条件下对醇类的氧化进行了研究。结果表明,在所用实验条件下,Mn(Ⅲ)可以方便地在电极上生成及再生,对苄醇类及二级脂肪醇类能高产率地选择性氧化成相应的羰基化合物。
Indirect electrooxidation of alcohols was studied by using Mn(Ⅲ)/Mn(Ⅱ) as a redox system under phase transfer catalysis. The results showed that this system exhibits better selectivity and activity for oxidation of benzyl alcohols and aliphatic secondary alcohols.
出处
《合成化学》
CAS
CSCD
1993年第3期244-247,267,共5页
Chinese Journal of Synthetic Chemistry
基金
河南省自然科学基金
关键词
醇
选择性
相转移催化
电氧化
Alcohol, Selectivity, Phase transfer catalysis, Electrial oxidation, Manganese(Ⅲ)/Manganese(Ⅱ).
