摘要
A continuous mixed flow reactor, in which the supported heteropolyacid catalyst HRP-12 was suspended, was adopted in the experiment. Experimental data were used in parameters estimation for kinetics equation of benzene alkylation with linear olefin. Parameters, including reaction rate constant, activation energy and reaction order in olefin molar concentration, were determined as 13530s-1, 48743Jmol-1 and 1 respectively. The kinetic equation for benzene alkylation with linear olefin was thus established. Statistics test and model prediction have shown that the kinetics equation is highly credible under the condition α=0.05 and well corresponds with reaction principle.
A continuous mixed flow reactor, in which the supported heteropolyacid catalyst HRP-12 was suspended, was adopted in the experiment. Experimental data were used in parameters estimation for kinetics equation of benzene alkylation with linear olefin. Parameters, including reaction rate constant, activation energy and reaction order in olefin molar concentration, were determined as 13530s^(-1), 48743Jmol^(-1) and 1 respectively. The kinetic equation for benzene alkylation with linear olefin was thus established. Statistics test and model prediction have shown that the kinetics equation is highly credible under the condition α=0.05 and well corresponds with reaction principle.
出处
《燃料化学学报》
EI
CAS
CSCD
北大核心
2004年第5期636-640,共5页
Journal of Fuel Chemistry and Technology
基金
国家重点基础研究发展规划项目(G2000048006)。~~
关键词
负载杂多酸催化剂
苯
直链烯烃
烷基化
动力学
supported heteropolyacid catalyst
benzene
linear olefin
alkylation
kinetics
