摘要
Green single crystal of the title compound was accidentally obtained by the reaction of N,N′-bis(pyridylcarbonyl)-4,4′-diaminodiphenyl ether (L) with nickel perchlorate. In the structure of [Ni( ì3-OH)( ì3-ClO4)(H2O)]n, the local coordinating geometry around Ni center displays a distorted octahedron in which one coordination site of each metal atom was occupied by a water molecule. Each perchlorate anion and hydroxyl group acts as a tridentate bridging spacer to bind three Ni atoms, thus resulting in the formation of two-dimensional layered network. CSD: 414263.
Green single crystal of the title compound was accidentally obtained by the reaction of N,N′-bis(pyridylcarbonyl)-4,4′-diaminodiphenyl ether (L) with nickel perchlorate. In the structure of [Ni( ì3-OH)( ì3-ClO4)(H2O)]n, the local coordinating geometry around Ni center displays a distorted octahedron in which one coordination site of each metal atom was occupied by a water molecule. Each perchlorate anion and hydroxyl group acts as a tridentate bridging spacer to bind three Ni atoms, thus resulting in the formation of two-dimensional layered network. CSD: 414263.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2004年第11期1375-1376,共2页
Chinese Journal of Inorganic Chemistry
基金
国家重点基础研究发展规划资助项目(No.G2000077500)
国家自然科学基金资助项目
关键词
晶体结构
镍
羟基
高氯酸根
水合物
crystal structure nickel hydroxyl group perchlorat
