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Recent Research Progress of Chemical Reactions under Supercritical Conditions 被引量:1

Recent Research Progress of Chemical Reactions under Supercritical Conditions
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摘要 Chemical reactions (such as hydrogenation, hydroformylation, alkylation, esterification, etc.) at supercritical conditions afford opportunities to manipulate the solubility of reactants and products, to eliminate interphase transport limitations in the reaction systems, and to be beneficial to the environment. This review concentrates on the most recent developments after 2001 with only a brief summary of pioneering research work before 2001. Chemical reactions (such as hydrogenation, hydroformylation, alkylation, esterification, etc.) at supercritical conditions afford opportunities to manipulate the solubility of reactants and products, to eliminate interphase transport limitations in the reaction systems, and to be beneficial to the environment. This review concentrates on the most recent developments after 2001 with only a brief summary of pioneering research work before 2001.
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第4期498-504,共7页 中国化学工程学报(英文版)
基金 the National Key Fundamental Research Project (No. G2000048009) SINOPEC, China.
关键词 化学反应 超临界状态 环境保护 环境污染 SCFs 分离 浓缩 绿色化学 可持续发展 chemical reactions, supercritical fluids, environmentally benign process
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  • 1Bhalchandra M. Bhanage,Yutaka Ikushima,Masayuki Shirai,Masahiko Arai.The selective formation of unsaturated alcohols by hydrogenation of α,β-unsaturated aldehydes in supercritical carbon dioxide using unpromoted Pt/Al2O3 catalyst[J].Catalysis Letters (-).1999(2-4)

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