角重叠模型及其在过渡元素配合物中的应用

Angular Overlap Model and Applications of It to Transition-Metal Complexes

本文对角重叠模型作简要介绍,并用它来解释过渡元素配合物的一些性质.如四配位体的几何构型;分子轨道稳定化能;二价过渡元素离子水化热等.

This paper briefly introduces the angular overlap model, and on the basis of it, explains some poperties of the transition metal complex, such as the four ligands geometric type; molecular orbitol stabilization energy; Heats of hydration of divalent transition metal cations .