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热压快速凝固Fe_(0.92)Mn_(0.08)Six半导体的热电性能 被引量:3

Transport Properties of Fe_(0.92)Mn(0.08)Six Semiconductor Prepared by Rapid Solidification and Hot Pressing
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摘要 采用快速凝固和热压的方法制备了p型热电材料Fe0.92Mn0.08Six(x=1.9,2.0,2.1,2.3,2.5)。X射线衍射分析表明,热压试样退火24h后,完全转变为半导体相。所有试样的致密度均高于90%。测量试样的电学性能发现,原料配比为Fe0.92Mn0.08Si2.1的试样在整个测量温度范围内的功率因子最大,550℃时达到了400Wm-1K-1以上。 P-type Fe0.92Mn0.08Six(x=1.9, 2.0, 2.1, 2.3, 2.5) alloys were prepared by rapid solidification and hot pressing. XRD analysis revealed that for all samples the phases were converted into a single beta phase after being annealed for 24 h at 800 degreesC. The density of all the samples is over 90%. The experimental results showed that Fe0.92Mn0.08Si2.1 had the highest power factor over the whole measured temperature range greater than 400 muW(.)m(-1.)K(-1) at 550degreesC.
机构地区 浙江大学
出处 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2004年第9期980-983,共4页 Rare Metal Materials and Engineering
基金 国家自然科学基金项目(59971004)
关键词 快速凝固 试样 热压 退火 致密度 功率因子 X射线衍射分析 半导体 热电性能 热电材料 Fe0.92Mn0.08Si rapid solidification hot pressing power factor
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  • 1I Yamauchi,H Okamoto,A Suganuma,I Ohnaka. Effects of Cu addition on the β-phase formation rate in Fe2Si5 thermoelectric materials[J] 1998,Journal of Materials Science(2):385~394
  • 2I YAMAUCHI,A SUGANUMA,T OKAMOTO,I OHNAKA. Effect of copper addition on the β-phase formation rate in FeSi2 thermoelectric materials[J] 1997,Journal of Materials Science(17):4603~4611
  • 3高敏,D.M.Rowe.适用于25—600℃温度范围的温差电动势率和电阻率测试系统[J].红外技术,1990,12(2):38-41. 被引量:2

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