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新型Q相高铝水泥的烧成条件 被引量:12

SINTERING CONDITIONS OF Q PHASE-BEARING HIGH ALUMINA CEMENT
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摘要 将高铝水泥中的惰性成分硅铝酸二钙(C2AS)转化为水化活性良好的Q相,组成Q相铝酸一钙(CA)七铝酸十二钙(C12A7)高铝水泥系统,对此系统的烧成条件进行研究。研究表明:在Q相CAC12A7高铝水泥系统中,Q相在1260℃开始生成,随着温度的升高,Q相的生成量逐渐增大。在1300℃时,随着保温时间的延长,Q相的生成量逐渐增大;超过1300℃,试样开始融化;Q相CAC12A7高铝水泥具有早期强度高,中后期强度仍在发展且不倒缩等特点。 In the high alumina cement, dicalcium aluminate silicate is transformed into Q phase. The system becomes Q phase-bearing high alumina cement in the form of Q phase-monocalcium aluminate-12:7 calcium aluminate. Sintering conditions are investigated. Results show that Q phase is formed when the temperature of systems is above 1260°C. The content of Q phase increases along with increasing temperature and extending time in 1300°C. The sample melts above 1300°C. The cement has a higher early strength and the compressive strength is developed in middle and late period.
出处 《硅酸盐学报》 EI CAS CSCD 北大核心 2004年第10期1289-1292,共4页 Journal of The Chinese Ceramic Society
基金 武汉理工大学硅酸盐材料工程教育部重点实验室开放基金 (SYSJJ2 0 0 3 -0 3 )资助项目
关键词 高铝水泥 Q相 烧成条件 水化性能 Alumina Compressive strength Hydration Microstructure X ray diffraction analysis
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参考文献4

  • 1[1]PARKER T W,RYDER J F.Proceeding.The quaternary phase in high-alumina cement.In:The 3rd International Congress on the Chemistry of Cement in London.London: The Cement and Concrete Association,1954.485-489.
  • 2[2]GLASSER F P,MARR J.Quaternary phase in the system CaOMgOAl2O3SiO2 .Trans Br Ceram Soc,1975,74 :113-119.
  • 3[3]KAPRALIK I,HANIC F.Studies of the system CaOMgOAl2O3SiO2 in relation to the quaternary phase Q.Trans Br Ceram Soc,1980,79:128-133.
  • 4[4]AKHMETOV I S,MLRYUK O A.Phase transformation when synthesizing clinkers produced of technogeneous new materials.9th International Congress on the Chemistry of Cement[C],New Delhic,India,1992.74-80.

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