摘要
The title compound, [Cu(4,4-bpy)(H2O)4](C4H2O4)(H2O)4 1, has been syn- thesized by the reaction of Cu(NO3)23H2O with 4,4-bipyridine and fumaric acid, and structurally characterized by X-ray diffraction analysis. Its crystal structure belongs to monoclinic, space group C2/c with a = 16.6350(5), b = 11.1667(2), c = 13.1371(4) ? = 125.144(1), C14H26CuN2O12, Mr = 477.91, Z = 4, V = 1995.47(9) 3, Dx = 1.591 g/cm3, m = 1.160 mm-1, F(000) = 996, R = 0.0331 and wR = 0.0883 for 1765 observed reflections (I > 2(I)). A two-dimensional network is formed in complex 1 through the hydrogen bonds and VDW interactions.
The title compound, [Cu(4,4-bpy)(H2O)4](C4H2O4)(H2O)4 1, has been syn- thesized by the reaction of Cu(NO3)23H2O with 4,4-bipyridine and fumaric acid, and structurally characterized by X-ray diffraction analysis. Its crystal structure belongs to monoclinic, space group C2/c with a = 16.6350(5), b = 11.1667(2), c = 13.1371(4) ? = 125.144(1), C14H26CuN2O12, Mr = 477.91, Z = 4, V = 1995.47(9) 3, Dx = 1.591 g/cm3, m = 1.160 mm-1, F(000) = 996, R = 0.0331 and wR = 0.0883 for 1765 observed reflections (I > 2(I)). A two-dimensional network is formed in complex 1 through the hydrogen bonds and VDW interactions.
基金
This work was supported by the State Key Basic Research and Development Plan of China(001CB108906)
the NNSFC(No.20173063)
NSF of Fujian Province(E0020001)
