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Diffusion-Controlled Adsorption Kinetics of Triton X-100 at Air/Solution Interface

Diffusion-Controlled Adsorption Kinetics of Triton X-100 at Air/Solution Interface
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摘要 In this paper, the equilibrium surface tension and the dynamic surface tension of aqueous Triton X-100 solution at temperature 25 ℃ were measured by means of Wilhelmy plate method and maximal bubble pressure method respectively. The determined critical micellar concentration(cmc) of Triton X-100 at 25 ℃ is (2.2×10-4) mol/dm3. The adsorption mechanics of Triton X-100 at air/solution was determined. For the submicellar concentrations it is diffusion-controlled. The diffusion coefficient was calculated from the experimental data in the range of short limit. In the range of long time adsorption, the subsurface concentration is fitted from the measured dynamic surface tensions. In this paper, the equilibrium surface tension and the dynamic surface tension of aqueous Triton X-100 solution at temperature 25 ℃ were measured by means of Wilhelmy plate method and maximal bubble pressure method respectively. The determined critical micellar concentration(cmc) of Triton X-100 at 25 ℃ is (2.2×10^(-4)) mol/dm^(3). The adsorption mechanics of Triton X-100 at air/solution was determined. For the submicellar concentrations it is diffusion-controlled. The diffusion coefficient was calculated from the experimental data in the range of short limit. In the range of long time adsorption, the subsurface concentration is fitted from the measured dynamic surface tensions.
机构地区 School of Sciences
出处 《Transactions of Tianjin University》 EI CAS 2004年第3期214-216,共3页 天津大学学报(英文版)
关键词 传播控制吸附动力学 动态表面张力 最大气泡压力方法 气液表面 表面活性剂 diffusion-controlled adsorption kinetics dynamic surface tension maximum bubble pressure method
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参考文献2

  • 1J. Liu,U. Messow.Diffusion-controlled adsorption kinetics at the air/solution interface[J].Colloid & Polymer Science.2000(2)
  • 2Dr. R. Miller,Prof. Dr. G. Kretzschmar.Numerische L?sung für ein gemischtes Modell der diffusions-kinetik-kontrollierten Adsorption[J].Colloid and Polymer Science Kolloid - Zeitschrift & Zeitschrift für Polymere.1980(1)

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