摘要
以强酸性阳离子交换树脂为催化剂,对环戊烯水合制环戊醇反应的本征动力学进行了研究。在此基础上,排除内外扩散对水合反应的影响因素后,采用高斯-牛顿法,根据试验数据进行参数估算,得到了本征动力学模型参数。统计检验结果表明,所建立的动力学模型是适当的,可近似描述环戊烯水合制取环戊醇的反应过程。
The intrinsic kinetics of the hydration reaction of cyclopentene was investigated in the presence of a strong acidic cation exchange resin catalyst. After ruled out the influence factors of internai and external diffustions on the hydration reaction, parameters of the intrinsic kinetics model were solved by the Gauss-Newton method based on the experimental data. The intrinsic kinetics model was proved to be adequate from the static inspection, which could approximately describe the reaction path of cyclopentene hydration for cyclopentanol.
出处
《石油炼制与化工》
CAS
CSCD
北大核心
2004年第9期34-37,共4页
Petroleum Processing and Petrochemicals
