绝热式热动力学的研究 Ⅳ.可逆反应的热谱解析

Studies on Adiabatic Thermokinetics Ⅳ. Thermokinetic Research of Reversible Reactions

本文建立了可逆反应在绝热系统中的热动力学研究法,并用自制的绝热式自动热量计,研究了三个可逆反应体系的热动力学,验证了本文方法的正确性。

An adiabatic thermokinetic research method of the reversible reactions is proposed and has been used to study three reversible reaction systems in this paper. Both rate constants and equilibrium constants of these reactions calculated are in agreement with the values in literatures. And therefore, the validity of this method and its theoretical basis should be proved.