摘要
A new cobalt vanadate compound 1 [CoII(H2O)2V2VO6] has been hydrothermally synthesized and characterized by the elemental analyses and the single crystal X-ray diffraction analysis. Compound 1 crystallizes in the orthorhombic system, space group Pmna, with a=0.55646, b=1.06900, c=1.18452 nm, and Z=4. The magnetic susceptibility of the cobalt vanadate has been measured and indicates possible antiferromagnetic coupling between adjacent cobalt (II) (0.54320.5697 nm) through bond or space.
A new cobalt vanadate compound 1 [CoII(H2O)2V2VO6] has been hydrothermally synthesized and characterized by the elemental analyses and the single crystal X-ray diffraction analysis. Compound 1 crystallizes in the orthorhombic system, space group Pmna, with a=0.55646, b=1.06900, c=1.18452 nm, and Z=4. The magnetic susceptibility of the cobalt vanadate has been measured and indicates possible antiferromagnetic coupling between adjacent cobalt (II) (0.54320.5697 nm) through bond or space.
基金
Project supported by the National Natural Science Foundation of China (No. 20274006).
