期刊文献+

不同粒度碳材料对K_2FeO_4放电性能的影响 被引量:3

The effect of carbon materials with different grain size and their content on the discharge capability of K_2FeO_4 electrode
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摘要 应用扫描电镜或透射电镜分析了不同粒度碳材料(包括石墨、膨化石墨和乙炔黑)的形貌,并着重研究了这些导电剂及其含量对K2FeO4放电性能的影响。研究结果表明,当K2FeO4电极中碳类导电剂含量较低时,粒度较小的导电剂对其放电性能改善较为显著;而当碳类导电剂含量较高时,则是粒度较大的导电剂有利于K2FeO4电极放电。 The morphology of the carbon materials, including graphite, expanded graphite, acetylene black, were analyzed using scanning electron microscopy (SEM) or transmission electron micrograph (TEM). The effects of carbon materials and their content on the discharge capability of K2FeO4 electrode were mainly studied in this paper. Studies show that carbon materials with smaller grain size can remarkably improve the discharge performance of K2FeO4 when their contents are lower in the electrode. However, carbon materials with larger grain size are advantageous to improving the discharge performance of K2FeO4 electrode when the electrode contains more carbon materials.
出处 《电源技术》 CAS CSCD 北大核心 2004年第9期555-557,共3页 Chinese Journal of Power Sources
基金 :国家自然科学基金资助项目(50172041)
关键词 K2FeO4 放电性能 碳材料 电极 石墨 形貌 改善 导电剂 粒度 乙炔黑 K2FeO4 carbon material discharge capability
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参考文献10

  • 1JIANG J Q, BARRY L, LUMINITA Q. Preparation and evaluation of potassium ferrate as an oxidant and coagulant for potable water treatment [J]. Environ Eng Sci, 2001,18(5):323-328.
  • 2WeiHuaYANG,JianQingZHANG,等.Studies on the Electrochemical Characteristics of K_2FeO_4 Electrode[J].Chinese Chemical Letters,2002,13(8):761-764. 被引量:8
  • 3YANG W H, WANG J M, PAN T, et al. Studies on the electrochemical characteristics of K2Sr(FeO4)2 electrode [J]. Electrochem Commun, 2002,4:710-715.
  • 4LIONEL D, PIERRE L. A novel oxidizing reagent based on potassium ferrate (Ⅵ) [J]. J Org Chem, 1996,61(12):6 360-6 370.
  • 5LICHT S, WANG B H, GHOSH S. Energetic iron (Ⅵ) chemistry: the super-iron battery[J]. Science, 1999,285:1 039- 1 042.
  • 6LICHT S, VERA N, SUSANTA G, et al. SrFeO4: Synthesis, Fe (Ⅵ)characterization and the strontium super-iron battery [J].Electrochem Commun, 2001,3:340-345.
  • 7LICHT S, SUSANTA G. High power BaFe(Ⅵ)O4/MnO2 composite cathode alkaline super-iron batteries [J]. J Power Sources, 2002,109:465-468.
  • 8LICHT S, WANG B H, GHOSH S, et al. Enhanced Fe (Ⅵ) cathode onductance and charge transfer: effects on the super-iron battery[J]. Electrochem Commun, 2000,2:535-540.
  • 9杨长春,石秋芝,侯宏英.碱性高铁电池的初步研究[J].电源技术,2002,26(4):293-297. 被引量:11
  • 10武彩霞,夏天,汪继强.新型正极材料K_2FeO_4的制备及其应用[J].电源技术,2002,26(5):360-364. 被引量:4

二级参考文献17

  • 1毛宗强,张纯,阎军.国外电动汽车用金属-空气电池[J].电源技术,1996,20(6):252-255. 被引量:8
  • 2[1]LICHT S, WANG B, GHOSH S. Energetic iron(Ⅳ) chemistry:the super-iron battery[J]. Science, 1999,285:1 039.
  • 3[2]LICHT S. Iron-based storage battery[P]. US:6033343, 2000-03-07.
  • 4[3]LICHT S, WANG B, GHOSH S, et al. Insoluble compounds:effects on the super-iron battery. Electrochem Commun, 1999,(1):522.
  • 5[4]LICHT S, WANG B, GHOSH S, et al. Enhanced Fe (Ⅵ) cathode conductance and charge transfer:effects on the super-iron battery[J]. Electrochem Commun, 2000,(2):535.
  • 6[5]LICHT S, WANG B. Nonaqueous phase Fe(Ⅵ) electrochemical storage and discharge of super-iron/lithium primary batteries[J]. Electrochemical and Solid-State Letters, 2000,3(5):209.
  • 7[6]LICHT S, WANG B, XU G, et al. Solid phase modifiers of the Fe(Ⅵ) cathode:effects on the super-iron battery[J]. Electrochem Commun, 1999,(1):527.
  • 8[1]D. Lionel, L. Pierre, J. Org. Chem., 1996, 61, 6360.
  • 9[2]F. R. John, D. B. Kelly, A. M. Stephanie, J. W. Keith, Inorg. Chem. Acta, 1998, 267, 159.
  • 10[3]D. G. Lee, H. F. Gai, J. Chem., 1993, 71, 1394.

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