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二苯甲胺的制备 被引量：4

Preparation of Benzhydrylamine
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摘要 Benzhydrylamine was synthesized from benzophenoneoxime formed by oximation of benzophenone inan overall yield of 83.5%. The reduction took place with Zn in 20% NaOH solution at 100℃ for 7h in a yield of 84.7% andpurity of 99.1%. Benzhydrylamine was synthesized from benzophenoneoxime formed by oximation of benzophenone inan overall yield of 83.5%. The reduction took place with Zn in 20% NaOH solution at 100℃ for 7h in a yield of 84.7% andpurity of 99.1%.
作者 张珍明
机构地区 江苏省中医学校
出处 《中国医药工业杂志》 CAS CSCD 北大核心 2004年第8期461-461,共1页 Chinese Journal of Pharmaceuticals
关键词 二苯甲胺 制备 二苯甲酮 盐酸羟胺 二苯酮肟 NAOH水溶液 Zn粉 还原 benzhydrylamine benzophenone oxime intermediate synthesis
分类号 TQ246.31 [化学工程—有机化工]
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参考文献3

  • 1Weiberth FJ, Hall SS. Tandem alkylation-reduction of nitriles.Synthesis of branched primary amines [J]. J Org Chem, 1986,51 (26): 5338-5341.
  • 2Blatt AH. Organic Synthesis [M]. Coll Vol II, New York: John Wiley, 1955.70-71.
  • 3Ingold CK, Wilson CL. Optical activity in relation to tautomeric change. Part Ⅰ. Conditions underlying the transport of the centre of asymmetry in tautomeric systems [J]. J Chem Soc, 1933, 1493-1505.

同被引文献24

  • 1孙晋瑞,国大亮,卢珺.阿折地平的合成[J].齐鲁药事,2005,24(6):365-366. 被引量：1
  • 2The Halcon SD Group,Inc.Process for the production of variable amounts of DPA an aniline using only phenol and ammonia as the feedstock[P].US:4480127.1988-10-31.
  • 3Uniroyal Chemical Company IncMiddle buryConn.Process for the production of diphenylamine[P].US:4814504.1989.
  • 4日本洲化学工业株式会社.二苯胺的制造方法[P].日本专利,昭57-48946.1982.
  • 5Roebrt A S,Stanley E W,Polyfluorodiazo Compounds II1-phenyl-2,2,2,-trifluorodiazoethane[J].Journal of organic chemistry1967,32,3197-3199.
  • 6Li D,Saadat A,Cynthia A F.Microwave-accelerated reductive amination between ketones and ammonium acetate[J].Tetrahedron Letters,2010,51,5210-5212.
  • 7Mikhail B.Improved method for the synthesis of subtituted formylamines and substituted amines[P].WO2009018353(A1).
  • 8Zhang D M, Miyase T, Kuroyanagi M, et al. Oligosaccha ride polyesters from roots of Polygala glimerata[J]. Phyto- chemistry, 1998,47(1) ..45-52.
  • 9Navia J L, Roberts R A, Wingard R E. Study on the selec- tivity of bcnzoylation of metal chelates of sucrose [J]. J Carbohydr Chem, 1995,14(45) :465-480.
  • 10Cheng M C, Li C Y, Ko H C, et al. Antidepress antprinci- ples of the roots of Polygala tenuifolia[J]. J Nat Prod, 2006,69 : 1305-1309.

引证文献4

二级引证文献2

中国医药工业杂志
2004年 第8期

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