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Kinetics of crystal growth on seeded precipitation of sodium aluminate solutions with new device 被引量:2

Kinetics of crystal growth on seeded precipitation of sodium aluminate solutions with new device
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摘要 A new device was designed,which can effectively avoid the undesired nucleation and agglomeration of fine particles on the experimental results during the sead ed precipitation of sodium aluminate solution,and moreover,the experimental co nditions are nearly kept constant during the experiment. With the new device,it is proven that a good result can be obtained on the kinetics study of the cryst al growth in seeded precipitation of sodium aluminate solution.Experiments were carried out with the concentration of Na2O (Nk)170 g/L,the mole ratio of Na2O to Al2O3 (αk) all between 1.52 to 2.01,at 65,70,75 ℃,respectively. And the kinetics equation of crystal growth of gibbsite was deduc ed. A new device was designed,which can effectively avoid the undesired nucleation and agglomeration of fine particles on the experimental results during the sead ed precipitation of sodium aluminate solution,and moreover,the experimental co nditions are nearly kept constant during the experiment. With the new device,it is proven that a good result can be obtained on the kinetics study of the cryst al growth in seeded precipitation of sodium aluminate solution.Experiments were carried out with the concentration of Na_2O (N_k)170 g/L,the mole ratio of Na_2O to Al_2O_3 (α_k) all between 1.52 to 2.01,at 65,70,75 ℃,respectively. And the kinetics equation of crystal growth of gibbsite was deduc ed.
出处 《中国有色金属学会会刊:英文版》 CSCD 2004年第4期824-828,共5页 Transactions of Nonferrous Metals Society of China
基金 Project(G19990 64 90 2 )supportedbytheNationalBasicResearchProgramofChina project(5 98740 3 1)supportedbytheNationalNaturalScienceFoundationofChina
关键词 铝酸钠溶液 晶种分解 晶体生长 氧化铝 动力学 sodium aluminate solution seeded precipitation crystal growth kinetics
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同被引文献24

  • 1张江峰,李旺兴,尹周澜,陈启元.铝酸钠溶液晶种分解附聚过程主要影响因素研究[J].轻金属,2004(9):17-19. 被引量:16
  • 2陈念贻,柳妙修,周佩芳.铝酸钠溶液中NaOH活度的测定[J].轻金属,1993(2):22-23. 被引量:3
  • 3LI Yan, ZHANG Yi-fei, YANG Chao, ZHANG Yi. Precipitatingsandy aluminium hydrox.ide from sodium aluminate solution bythe neutralization of sodium bicarbonate [J]. Hydrometallurgy,2009,98: 52-57.
  • 4VEESLER S, BOISTELLE R. About supersaturation and growthrates of hydrargillite Al(OH)3 in alumina caustic solutions [J].Journal of Crystal Growth, 1993, 130(3/4): 411-415.
  • 5PAULAIME A M, SEYSSIECQ I,VEESLER S. The influenceof organic additives on the crystallization and agglomeration ofgibbsite [J]. Powder Technology, 2003, 130: 345-351.
  • 6SEYSSIECQ I,VEESLER S,BOISTELLE R, LAMERANT J M.Agglomeration of gibbsite Al(OH)3 crystals in Bayer liquors:Influence of the process parameters[J]. Chemical EngineeringScience, 1998,53(12):2177-2185.
  • 7ZHANG Jiang-feng, YIN Zhou-lan, LI Wang-x.ing, YIN Jian-guo.Influence of the process conditions on agglomeration during theseeded precipitation of sodium aluminate solution [J]. LightMetals, 2005:215-217.
  • 8PRESTIDGE C A, AMETOV I. Cation effects duringaggregation and agglomeration of gibbsite particles undersynthetic Bayer crystallisation conditions [J]. Journal of CrystalGrowth, 2000,209(4): 924-933.
  • 9CHEN Qi-yuan, YIN Jian-guo, YIN Zhou-lan. Effect ofmechanically activated seeds on the agglomeration process ofsupersaturated sodium aluminate liquors [J]. Light Metals,2007:157-161.
  • 10ILIEVSKI D, LIVK I. An agglomeration efficiency model forgibbsite precipitation in a turbulently stirred vessel [J]. ChemicalEngineering Science, 2006, 61(6): 2010-2022.

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