线性低价铂系金属簇合物的研究

Recent Developments in Linear Chain Clusters of Low-Valent Platinum Group Metals

长链线性配合物具有特有的结构、成键和性质 ,在分子器件和特殊性能低维材料等方面展示出潜在的应用前景。在低价状态下 ,铂系金属可自聚合形成一类含有多个金属原子的线性金属链式簇合物。本文就有关线性低价铂系金属簇合物的研究进展作一简述。

There are considerable interests in linear chain clusters because of the polynuclear metal-metal bonding, structures, potential applications as molecular wires and low-dimensional materials with unusual properties. In the low oxidation states, platinum group metals have a tendency of aggregating to form clusters containing polynuclear metal chain. The progress in linear chain clusters of low-valent platinum group metals is briefly reviewed.